Oliver Wild, Pakpong Pochanart, and Hajime Akimoto
Frontier Research System for Global Change, Yokohama, Japan.

Long-range transport of air across the European and Asian continents brings substantial quantities of ozone and other oxidants to northeast Asia from upwind sources over Europe and North America. This transport differs significantly from that over the Pacific and Atlantic Oceans due to weaker and less frequent frontal systems over the continent and to weaker convective lifting over European sources. Slower O₃ formation, faster destruction at low altitudes, and greater deposition over continental regions lead to Europe having a smaller impact on O₃ than other source regions. We present chemical transport model studies of the formation and transport of O₃ from European precursor sources and investigate the extent of their impacts over Eurasia. We focus on measurement sites at 100^oE, representing the inflow to East Asia on which regional pollutant sources build, and on northeast Asia which may be directly affected by transport across Eurasia. The seasonality in O₃ production over Europe is simulated well, and transport principally in the boundary layer propagates these changes in O₃ over Eurasia, leading to monthly mean impacts at Mondy, Siberia, of 0.5-3.5 ppbv. Impacts over Japan are smaller, 0.2-2.5 ppbv, and are very similar to those from North American sources, which dominate at higher altitudes. By following the effect of daily emissions independently, we clearly demonstrate that this greater North American impact is associated with lifting over the Atlantic. European and North American sources contribute to background O₃ over Japan in the anticyclonic conditions which favour regional O₃ build-up, and are thus expected to have a small but significant effect on regional air quality. Finally, we demonstrate that location and transport lead to European sources having a different impact on OH, and hence on tropospheric oxidising capacity and climate, from other major northern hemisphere source regions.

J. Geophys. Res., 109, D11302, doi:10.1029/2003JD004501, 2004 (PDF, 1.3 Mb)

(Submitted: 30 December 2003; Revised: 13 March 2004; Accepted: 14 April 2004; Published 2 June 2004)